Free PDF Stereoelectronic Effects (Oxford Chemistry Primers)
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Stereoelectronic Effects (Oxford Chemistry Primers)
Free PDF Stereoelectronic Effects (Oxford Chemistry Primers)
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Review
`The subject is presented authoritatively, systematically and concisely without resort to mathematical treatment. As this subject is often given little coverage in textbooks or organic chemistry this text is to be welcomed.'Aslib Book Guide, vol.61, no.11, November 1996`This book is a useful introduction to stereo-electronic effects in organic chemistry. The style is engaging ... this book is an excellent supplementary text for undergraduates. Sponsorship for the series by Zeneca also ensures that it is extremely good value for money.'Chemistry in Britain, September 1997`engaging critique of biography .... enjoyable and thought provoking'New Scientist
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From the Back Cover
This series of short texts provides accessible accounts of a range of essential topics in chemistry. Written with the needs of the student in mind, the Oxford Chemistry Primers offer just the right level of detail for undergraduate study, and will be invaluable as a source of material commonly presented in lecture courses yet not adequately covered in existing texts. All the basic principles and facts in a particular area are presented in a clear and straightforward style, to produce concise yet comprehensive accounts of topics covered in both core and specialist courses. Stereoelectronic effects - interactions between electronic orbitals in three dimensions - control the way that molecules are put together and the 'rules of engagement' which operate when they meet and react. An understanding of these effects will help the student develop a 'feel' for the nature of molecules and their capabilities, which is especially useful when considering reactivity. Although there are a vast numbers of reactions known, these may be grouped into a small number of mechanistic classes, then into a still smaller set of classes of stereoelectronic interaction. Stereoelectronic effects is deliberately non-mathematical in its approach, with reactions illustrated by real examples. It should provide the student with an understanding of fundamental relationships and a powerful but simple approach to thinking about Chemistry.
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Product details
Series: Oxford Chemistry Primers (Book 36)
Paperback: 96 pages
Publisher: Oxford University Press; 1 edition (July 18, 1996)
Language: English
ISBN-10: 0198558937
ISBN-13: 978-0198558934
Product Dimensions:
9.8 x 0.2 x 7.5 inches
Shipping Weight: 4 ounces (View shipping rates and policies)
Average Customer Review:
4.9 out of 5 stars
6 customer reviews
Amazon Best Sellers Rank:
#91,306 in Books (See Top 100 in Books)
If you are an organic synthesis student, then this is for you. It has enough information to get the point across and to introduce you to the ideas of HOMO-LUMO, while at the same time not overload you with excruciating details.
Product as described, fast shipping. Happy customer
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There are reference books like Fleming's Molecular Orbitals and Organic Chemical Reactions that gives a complete presentation of orbital interactions and professional monographs like the one by Deslongchamp's Stereoelectronic Effects in Organic Chemistry that gives a large number of examples from the literature. This slim volume by Kirby is neither of those. I first encountered this as a supplemental recommended text for sophomore organic chemistry at Harvard, where the curriculum emphasizes thinking about reactions in frontier orbital terms. I read it from cover to cover back then in a matter of days, but the well chosen examples left a deep impression on me for many years to come -- it helped me to think about molecules and transition states by always being aware of the orbitals involved and looking for stabilizing or destabilizing interactions as (possible) explanations for chemical phenomena.If you've never thought about chemistry in these terms, and you need to start doing so for an intermediate/advanced class, I recommend this book as the place to start. Even though it is woefully incomplete and somewhat non-rigorous at times, it gets to the essence of things expediently by quickly laying the ground rules for MO theory in the first chapter (without math) and then spending the rest of the book showing classic cases where orbital effects control the course of a reaction and/or determines molecular geometry. These examples give you a "feel" for how stereoelectronic arguments in organic chemistry typically work.
In the physical organic chemistry course I have been taking, we have been talking all about stereoelectronic effects and molecular orbitals. I was having trouble with frontier molecular orbital theory as it relates to stereoelectronic effects and was not finding helpful explanations in other texts I was consulting. A friend recommended I read Kirby, and I am so glad she did. Kirby offers in-depth explanations of stereoelectronic phenomena in a useful and understandable manner. This is a great addition to any organic chemist's library.
Kirby's Stereoelectronic effects provides a good introduction to the fundamentals of molecular orbital interactions. Makes a nice supplement to advanced organic chemistry texts that are deficient in this area
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